http://repository.iitr.ac.in/handle/123456789/8351| Title: | Ge(ii) cation catalyzed hydroboration of aldehydes and ketones |
| Authors: | Sinhababu S. Singh D. Sharma M.K. Siwatch R.K. Mahawar P. Nagendran S. |
| Published in: | Dalton Transactions |
| Abstract: | Well-defined germylene cations [(i-Bu) 2 ATI]GeOTf (4) and [(i-Bu) 2 ATIGe][GaCl 4 ] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate). © 2019 The Royal Society of Chemistry. |
| Citation: | Dalton Transactions (2019), 48(13): 4094-4100 |
| URI: | https://doi.org/10.1039/c8dt05121f http://repository.iitr.ac.in/handle/123456789/8351 |
| Issue Date: | 2019 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 14779226 |
| Author Scopus IDs: | 55350422800 57203808643 55800306400 37073566600 57201914602 6701694750 |
| Author Affiliations: | Sinhababu, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India Singh, D., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India Sharma, M.K., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India Siwatch, R.K., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India Mahawar, P., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India Nagendran, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110 016, India |
| Funding Details: | Dedicated to Prof. François P. Gabbaï. S. S., D. S., M. K. S., R. K. S. and P. M. thank the University Grants Commission (UGC), Indian Institute of Technology Delhi (IITD), and the Council of Scientific and Industrial Research (CSIR), New Delhi, India, for research fellowships. S. N. thanks the SERB, Department of Science and Technology (DST), New Delhi, India, for funding (SB/S1/IC-46/2013) and DST-FIST for establishing single crystal X-ray diffraction (SR/FST/CSII-027/2014) and HRMS (SR/FST/CS-1-195/2008) facilities in the Department of Chemistry, IIT Delhi. |
| Corresponding Author: | Nagendran, S.; Department of Chemistry, Indian Institute of Technology DelhiIndia; email: sisn@chemistry.iitd.ac.in |
| Appears in Collections: | Journal Publications [ECE] |
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