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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/8253
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dc.contributor.authorYadav D.-
dc.contributor.authorKumar Siwatch R.-
dc.contributor.authorSinhababu S.-
dc.contributor.authorKarwasara S.-
dc.contributor.authorSingh D.-
dc.contributor.authorRajaraman G.-
dc.contributor.authorNagendran S.-
dc.date.accessioned2020-10-09T05:07:50Z-
dc.date.available2020-10-09T05:07:50Z-
dc.date.issued2015-
dc.identifier.citationInorganic Chemistry (2015), 54(23): 11067-11076-
dc.identifier.issn201669-
dc.identifier.urihttps://doi.org/10.1021/acs.inorgchem.5b01436-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/8253-
dc.description.abstractUse of a substituted digermylene oxide as a ligand has been demonstrated through the isolation of a series of group 11 metal(I) iodide complexes. Accordingly, the reactions of digermylene oxide [{(i-Bu)2ATIGe}2O] (ATI = aminotroponiminate) (1) with CuI under different conditions afforded [({(i-Bu)2ATIGe}2O)2(Cu4I4)] (2) with a Cu4I4 octahedral core, [({(i-Bu)2ATIGe}2O)2(Cu3I3)] (3) with a Cu3I3 core, and [{(i-Bu)2ATIGe}2O(Cu2I2)(C5H5N)2] (4) with a butterfly-type Cu2I2 core. The reactions of compound 1 with AgI and AuI produced [({(i-Bu)2ATIGe}2O)2(Ag4I4)] (5) with a Ag4I4 octahedral core and [{(i-Bu)2ATIGe}2O(Au2I2)] (6) with a Au2I2 core, respectively. The presence of metallophilic interactions in these compounds is shown through the single-crystal X-ray diffraction and atom-in-molecule (AIM) studies. Preliminary photophysical studies on compound 6 are also carried out. © 2015 American Chemical Society.-
dc.language.isoen_US-
dc.publisherAmerican Chemical Society-
dc.relation.ispartofInorganic Chemistry-
dc.titleDigermylene Oxide Stabilized Group 11 Metal Iodide Complexes-
dc.typeArticle-
dc.scopusid14059154000-
dc.scopusid37073566600-
dc.scopusid55350422800-
dc.scopusid55800763800-
dc.scopusid57203808643-
dc.scopusid6602194731-
dc.scopusid6701694750-
dc.affiliationYadav, D., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.affiliationKumar Siwatch, R., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.affiliationSinhababu, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.affiliationKarwasara, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.affiliationSingh, D., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.affiliationRajaraman, G., Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400 076, India-
dc.affiliationNagendran, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India-
dc.description.correspondingauthorNagendran, S.; Department of Chemistry, Indian Institute of Technology DelhiIndia-
Appears in Collections:Journal Publications [ECE]

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