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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/8253
Title: Digermylene Oxide Stabilized Group 11 Metal Iodide Complexes
Authors: Yadav D.
Kumar Siwatch R.
Sinhababu S.
Karwasara S.
Singh D.
Rajaraman G.
Nagendran S.
Published in: Inorganic Chemistry
Abstract: Use of a substituted digermylene oxide as a ligand has been demonstrated through the isolation of a series of group 11 metal(I) iodide complexes. Accordingly, the reactions of digermylene oxide [{(i-Bu)2ATIGe}2O] (ATI = aminotroponiminate) (1) with CuI under different conditions afforded [({(i-Bu)2ATIGe}2O)2(Cu4I4)] (2) with a Cu4I4 octahedral core, [({(i-Bu)2ATIGe}2O)2(Cu3I3)] (3) with a Cu3I3 core, and [{(i-Bu)2ATIGe}2O(Cu2I2)(C5H5N)2] (4) with a butterfly-type Cu2I2 core. The reactions of compound 1 with AgI and AuI produced [({(i-Bu)2ATIGe}2O)2(Ag4I4)] (5) with a Ag4I4 octahedral core and [{(i-Bu)2ATIGe}2O(Au2I2)] (6) with a Au2I2 core, respectively. The presence of metallophilic interactions in these compounds is shown through the single-crystal X-ray diffraction and atom-in-molecule (AIM) studies. Preliminary photophysical studies on compound 6 are also carried out. © 2015 American Chemical Society.
Citation: Inorganic Chemistry (2015), 54(23): 11067-11076
URI: https://doi.org/10.1021/acs.inorgchem.5b01436
http://repository.iitr.ac.in/handle/123456789/8253
Issue Date: 2015
Publisher: American Chemical Society
ISSN: 201669
Author Scopus IDs: 14059154000
37073566600
55350422800
55800763800
57203808643
6602194731
6701694750
Author Affiliations: Yadav, D., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Kumar Siwatch, R., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Sinhababu, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Karwasara, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Singh, D., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Rajaraman, G., Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400 076, India
Nagendran, S., Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
Corresponding Author: Nagendran, S.; Department of Chemistry, Indian Institute of Technology DelhiIndia
Appears in Collections:Journal Publications [ECE]

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