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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/4137
Title: Hydrogen-bonding and Ï€-Ï€ Stacking inter-actions in tris-(1,10-phenanthroline-2 N,N′)nickel(II) bis-{[1-tert-butyl-imidazole-2(3H)-thione-S]trichloridonickelate(II)} acetonitrile disolvate
Authors: Singh U.P.
Aggarwal V.
Published in: Acta Crystallographica Section E: Structure Reports Online
Abstract: The asymmetric unit of the title complex, [Ni(C12H8N2)3][NiCl3(C7H12N2S)] 2·2CH3CN, consists of one anion, one-half of a cation and one acetonitrile mol-ecule. The NiII atom in the [Ni(phen)3]2+ cation (phen is 1,10-phenanthroline) lies on an inversion centre in an octa-hedral environment, whereas in the [NiCl3(tm)]- anion [tm is 1-tert-butyl-imidazole-2(3H)-thione], the geometry is distorted tetra-hedral. In the crystal structure, inter-molecular C - H⋯Cl hydrogen bonds and Ï€-Ï€ stacking inter-actions (centroid-centroid distance = 3.52 Ã…) lead to the formation of a three-dimensional framework. One of the methyl groups of the tert-butyl group of N-tert-butyl-2-thio-imidazole is disordered between two equally populated positions. © 2008.
Citation: Acta Crystallographica Section E: Structure Reports Online (2008), 64(7): m935-m936
URI: https://doi.org/10.1107/S1600536808018060
http://repository.iitr.ac.in/handle/123456789/4137
Issue Date: 2008
ISSN: 16005368
Author Scopus IDs: 57203181883
16444161100
Author Affiliations: Singh, U.P., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India
Aggarwal, V., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India
Corresponding Author: Singh, U. P.; Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India; email: udaipfcy@iitr.ernet.in
Appears in Collections:Journal Publications [CY]

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