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dc.contributor.authorSingh M.-
dc.contributor.authorAggarwal V.-
dc.contributor.authorSingh U.P.-
dc.contributor.authorSingh N.K.-
dc.date.accessioned2020-10-06T14:31:49Z-
dc.date.available2020-10-06T14:31:49Z-
dc.date.issued2009-
dc.identifier.citationPolyhedron (2009), 28(1): 195-199-
dc.identifier.issn2775387-
dc.identifier.urihttps://doi.org/10.1016/j.poly.2008.10.016-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/4132-
dc.description.abstractThe ligand N 2 -[bis(benzylsulfanyl)methylene]-2-methoxybenzohydrazide (N 2 -bmbh) (1) on reaction with CuCl 2 .2H 2 O yielded the mononuclear complex [Cu(bzsmp) 2 Cl 2 ] (2) (2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole, bzsmp). Complex 2 has been characterized by analytical, spectroscopic and X-ray data. X-ray study of 2 reveals that the cyclized ligand 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole (bzsmp) acts as neutral bidentate ligand to form six membered chelate ring and the presence of C-H⋯π (face to edge) and C-H⋯S and two type of C-H⋯Cl weak interactions. © 2008 Elsevier Ltd. All rights reserved.-
dc.language.isoen_US-
dc.relation.ispartofPolyhedron-
dc.subject1,3,4-Oxadiazole-
dc.subjectC-H⋯π interactions-
dc.subjectCu(II) complex-
dc.subjectCyclization-
dc.subjectX-ray-
dc.titleSynthesis, spectroscopic and crystal structure investigation of [Cu(bzsmp) 2 Cl 2 ];{bzsmp = 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole}: cyclization of N 2 -[bis(benzylsulfanyl)methylene]-2-methoxybenzohydrazide to 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4 -oxadiazole during complexation-
dc.typeArticle-
dc.scopusid15921656800-
dc.scopusid16444161100-
dc.scopusid57203181883-
dc.scopusid35412427900-
dc.affiliationSingh, M., Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 Uttar Pradesh, India-
dc.affiliationAggarwal, V., Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, Uttarakhand, India-
dc.affiliationSingh, U.P., Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, Uttarakhand, India-
dc.affiliationSingh, N.K., Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 Uttar Pradesh, India-
dc.description.fundingFinancial support [01(2152)07/EMR-II] from Council of Scientific and Industrial Research (CSIR), New Delhi, India is gratefully acknowledged. One of the authors (M. Singh) is thankful to CSIR, New Delhi, India for the award of SRE, supported by Grant No. 9/13(160) 2008/EMR-I and [01 (2152) 07/EMR-II]. Appendix A-
dc.description.correspondingauthorSingh, N.K.; Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 Uttar Pradesh, India; email: nksingh@bhu.ac.in-
Appears in Collections:Journal Publications [CY]

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