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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/4131
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dc.contributor.authorSingh M.-
dc.contributor.authorAggarwal V.-
dc.contributor.authorSingh U.P.-
dc.contributor.authorSingh N.K.-
dc.date.accessioned2020-10-06T14:31:49Z-
dc.date.available2020-10-06T14:31:49Z-
dc.date.issued2009-
dc.identifier.citationPolyhedron (2009), 28(1): 107-112-
dc.identifier.issn2775387-
dc.identifier.urihttps://doi.org/10.1016/j.poly.2008.10.015-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/4131-
dc.description.abstractA new dithioligand [N′-(2-methoxybenzoyl)hydrazinecarbodithioate] ethyl ester (H2mbhce, 1) formed complexes [M(Hmbhce)2]n {M = Mn(II), Cd(II)} which have been characterized with the help of elemental analyses, magnetic susceptibility measurements, IR, UV-Vis, 1H and 13C NMR and mass spectrometry. [Mn(Hmbhce)2]n (2) crystallized in monoclinic system with space group P21/n. In the polymeric structure of 2, the ligand acts as an uninegative tridentate N(1), O(1), S(3) donor and forms a five membered chelate ring with N(1), C(2) and O(1). The intermediate bond lengths (between single and double bond distances) O(1)-C(2) = 1.241(3), N(2)-C(2) = 1.325(3), N(1)-N(2) = 1.393(2), N(1)-C(8) = 1.311(3) Ǻ and C(8)-S(3) = 1.704(2) Å suggest considerable delocalization of charge which develops slightly aromatic character in the chelate ring. © 2008 Elsevier Ltd. All rights reserved.-
dc.language.isoen_US-
dc.relation.ispartofPolyhedron-
dc.subjectCarbodithioic acid ester-
dc.subjectCoordination polymer-
dc.subjectCrystal structure-
dc.subjectONS donor ligand-
dc.titleSynthesis, characterization and spectroscopic studies of a new ligand [N′-(2-methoxybenzoyl)hydrazinecarbodithioate] ethyl ester and its Mn(II) and Cd(II) complexes: X-ray structural study of Mn(II) complex-
dc.typeArticle-
dc.scopusid15921656800-
dc.scopusid16444161100-
dc.scopusid57203181883-
dc.scopusid35412427900-
dc.affiliationSingh, M., Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 UP, India-
dc.affiliationAggarwal, V., Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, Uttarakhand, India-
dc.affiliationSingh, U.P., Department of Chemistry, Indian Institute of Technology, Roorkee 247 667, Uttarakhand, India-
dc.affiliationSingh, N.K., Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 UP, India-
dc.description.fundingOne of the authors (M. Singh) is thankful to CSIR, New Delhi, India for the award of Direct SRF, supported by Grant No. 9/13(160)2008/EMR-I. Appendix A-
dc.description.correspondingauthorSingh, M.; Department of Chemistry, Banaras Hindu University, Varanasi, 221 005 UP, India; email: mamatasingh6@gmail.com-
Appears in Collections:Journal Publications [CY]

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