http://repository.iitr.ac.in/handle/123456789/4128
DC Field | Value | Language |
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dc.contributor.author | Singh U.P. | - |
dc.contributor.author | Aggarwal V. | - |
dc.date.accessioned | 2020-10-06T14:31:47Z | - |
dc.date.available | 2020-10-06T14:31:47Z | - |
dc.date.issued | 2009 | - |
dc.identifier.citation | Journal of Structural Chemistry (2009), 50(4): 663-670 | - |
dc.identifier.issn | 224766 | - |
dc.identifier.uri | https://doi.org/10.1007/s10947-009-0102-3 | - |
dc.identifier.uri | http://repository.iitr.ac.in/handle/123456789/4128 | - |
dc.description.abstract | The nickel(II) complexes dichlorobis(1-tert-butylimidazole-2-thione)nickel(II) [Ni(tmt-Bu)2Cl2] (1), dinitratobis(1-tert-butylimidazole-2-thione)nickel(II) [Ni(tmt-Bu)2(NO3)2] (2), dichloro-bis(3-phenyl-5-methyl-pyrazole)(1-tert-butylimidazole-2-thione)nickel(II) [Ni(pzPh,MeH)2(tmt-Bu)Cl2] (3) and dinitratobis(3-phenyl-5-methyl-pyrazole)(1-tert-butylimidazole-2-thione)nickel(II) [Ni(pzPh,MeH)2(tmt-Bu)(NO3)2] (4) have been synthesized and studied. The single crystal X-ray diffraction analysis was carried out for 1 and 4 {Bruker Kappa Apex-II CCD diffractometer, MoKα radiation}. Crystal data for 1: monoclinic C2/c, a = 16.949(2) Å, b = 8.6647(10) Å, c = 15.461(3) Å, β = 117.662(4)°, V = 2011.1(5) Å3, Z = 4, Dcalc = 1.460 g/cm3. Crystal data for 4: triclinic P-1, a = 9.9775(7) Å, b = 11.2254(8) Å, c = 14.8068(10) Å, α = 75.401(4)°, β = 87.422(4)°, γ = 74.874(4)°, V = 1548.86(19) Å3, Z = 2, Dcalc = 1.405 g/cm3. Coordination core of complex 1 adopts distorted tetrahedral geometry whereas core 4 has distorted octahedral geometry. The bonded nitrates are of two types coordinating as monodentate and bidentate ligands. © 2009 Springer Science+Business Media, Inc. | - |
dc.language.iso | en_US | - |
dc.relation.ispartof | Journal of Structural Chemistry | - |
dc.subject | 1-tert-butylimidazole-2-thione | - |
dc.subject | 3-phenyl-5-methyl-pyrazole | - |
dc.subject | Nickel(II) | - |
dc.subject | Non-covalent interactions | - |
dc.subject | Synthesis | - |
dc.title | Structural studies of nickel(ii) complexes with 1-tert-butylimidazole-2-thione and 3-phenyl-5-methyl-pyrazole ligands | - |
dc.type | Article | - |
dc.scopusid | 57203181883 | - |
dc.scopusid | 16444161100 | - |
dc.affiliation | Singh, U.P., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India | - |
dc.affiliation | Aggarwal, V., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India | - |
dc.description.correspondingauthor | Singh, U. P.; Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India; email: udaipfcy@iitr.ernet.in | - |
Appears in Collections: | Journal Publications [CY] |
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