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dc.contributor.authorSingh U.P.-
dc.contributor.authorAggarwal V.-
dc.date.accessioned2020-10-06T14:31:47Z-
dc.date.available2020-10-06T14:31:47Z-
dc.date.issued2009-
dc.identifier.citationJournal of Structural Chemistry (2009), 50(4): 663-670-
dc.identifier.issn224766-
dc.identifier.urihttps://doi.org/10.1007/s10947-009-0102-3-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/4128-
dc.description.abstractThe nickel(II) complexes dichlorobis(1-tert-butylimidazole-2-thione)nickel(II) [Ni(tmt-Bu)2Cl2] (1), dinitratobis(1-tert-butylimidazole-2-thione)nickel(II) [Ni(tmt-Bu)2(NO3)2] (2), dichloro-bis(3-phenyl-5-methyl-pyrazole)(1-tert-butylimidazole-2-thione)nickel(II) [Ni(pzPh,MeH)2(tmt-Bu)Cl2] (3) and dinitratobis(3-phenyl-5-methyl-pyrazole)(1-tert-butylimidazole-2-thione)nickel(II) [Ni(pzPh,MeH)2(tmt-Bu)(NO3)2] (4) have been synthesized and studied. The single crystal X-ray diffraction analysis was carried out for 1 and 4 {Bruker Kappa Apex-II CCD diffractometer, MoKα radiation}. Crystal data for 1: monoclinic C2/c, a = 16.949(2) Å, b = 8.6647(10) Å, c = 15.461(3) Å, β = 117.662(4)°, V = 2011.1(5) Å3, Z = 4, Dcalc = 1.460 g/cm3. Crystal data for 4: triclinic P-1, a = 9.9775(7) Å, b = 11.2254(8) Å, c = 14.8068(10) Å, α = 75.401(4)°, β = 87.422(4)°, γ = 74.874(4)°, V = 1548.86(19) Å3, Z = 2, Dcalc = 1.405 g/cm3. Coordination core of complex 1 adopts distorted tetrahedral geometry whereas core 4 has distorted octahedral geometry. The bonded nitrates are of two types coordinating as monodentate and bidentate ligands. © 2009 Springer Science+Business Media, Inc.-
dc.language.isoen_US-
dc.relation.ispartofJournal of Structural Chemistry-
dc.subject1-tert-butylimidazole-2-thione-
dc.subject3-phenyl-5-methyl-pyrazole-
dc.subjectNickel(II)-
dc.subjectNon-covalent interactions-
dc.subjectSynthesis-
dc.titleStructural studies of nickel(ii) complexes with 1-tert-butylimidazole-2-thione and 3-phenyl-5-methyl-pyrazole ligands-
dc.typeArticle-
dc.scopusid57203181883-
dc.scopusid16444161100-
dc.affiliationSingh, U.P., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India-
dc.affiliationAggarwal, V., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India-
dc.description.correspondingauthorSingh, U. P.; Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India; email: udaipfcy@iitr.ernet.in-
Appears in Collections:Journal Publications [CY]

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