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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3976
Title: Complete π-facial diastereoselectivity in Diels-Alder reactions of dissymmetric 2,4-cyclohexadienones
Authors: Hou H.-F.
Peddinti, Rama Krishna
Liao C.-C.
Published in: Organic Letters
Abstract: (Matrix presented) R = CH3 (b), CH=CH2 (c), ortho,endo.syn CH2CH=CH2 (d), Ph (e) predominant/major The studies in the Diels-Alder reactions of 5-methoxy-masked o-benzoquinone (1a, R = OMe) and simple dissymmetric 2,4-cyclohexadienones 1b-e with methyl vinyl ketone, styrene, and benzyl vinyl ether are described. The dienones 1b-e reacted with dienophiles to form syn adducts (dienophile approach is syn to allylic methoxy group) exclusively.
Citation: Organic Letters (2002), 4(15): 2477-2480
URI: https://doi.org/10.1021/ol020087o
http://repository.iitr.ac.in/handle/123456789/3976
Issue Date: 2002
ISSN: 15237060
Author Scopus IDs: 40861292200
6602375630
13406274100
Author Affiliations: Hou, H.-F., Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Peddinti, R.K., Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Liao, C.-C., Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan
Corresponding Author: Liao, C.-C.; Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan; email: ccliao@mx.nthu.edu.tw
Appears in Collections:Journal Publications [CY]

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