http://repository.iitr.ac.in/handle/123456789/3962| Title: | Magnesium chloride-catalyzed thiolysis of epoxides: Synthesis of β-hydroxy sulfides |
| Authors: | Rani R. Pattanayak S. Agarwal J. Peddinti, Rama Krishna |
| Published in: | Synthetic Communications |
| Abstract: | A mild and convenient ring opening of epoxides with thiophenol and its derivatives takes place at room temperature in the presence of magnesium chloride as catalyst to afford the corresponding β-hydroxy sulfides along with minor amounts of 2-chlorocycloalkanols in good yields. When the crude reaction mixtures are treated with aqueous sodium hydroxide solution, pure 2-arlythiocycloalkanols are obtained in good yields. © 2010 Taylor & Francis Group, LLC. |
| Citation: | Synthetic Communications (2010), 40(18): 2658-2666 |
| URI: | https://doi.org/10.1080/00397910903318625 http://repository.iitr.ac.in/handle/123456789/3962 |
| Issue Date: | 2010 |
| Keywords: | β-hydroxy sulfides Epoxides ring opening thiols |
| ISSN: | 397911 |
| Author Scopus IDs: | 16507511200 36453273400 56344053500 6602375630 |
| Author Affiliations: | Rani, R., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India Pattanayak, S., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India Agarwal, J., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India Peddinti, R.K., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India |
| Funding Details: | We thank the Department of Science and Technology (DST), New Delhi, for providing financial assistance. R. R. thanks the DST and J. A. thanks the University Grants Commission, New Delhi, for the fellowship awards. |
| Corresponding Author: | Peddinti, R. K.; Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India; email: rkpedfcy@iitr.ernet.in |
| Appears in Collections: | Journal Publications [CY] |
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