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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3692
Title: Di- and triphenyltin (iv) complexes of semi- and thiosemicarbazones
Authors: Nath, Mala
Sharma N.
Sharma C.L.
Published in: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Abstract: Five coordinated complexes of di- and triphenyltin (IV) moieties with semi- and thiosemicarbazones of furfuraldehyde, 2-methoxybenzaldehyde, 4-methoxybenzaldehyde, benzylmethylketone, benzil, salicylaldehyde, o-hydroxynaphthaldehyde and o-hydroxyacetophenone in 1:1 molar ratio have been synthesized and characterized on the basis of elemental analyses, conductance measurements, electronic, IR, Far IR, 1HNMR and mossbauer spectral studies. The non-electrolytic complexes are proposed to have distorted trigonal bipyramidal geometry around tin atoms with two equatorial and one axial phenyl groups in the triphenyltin complexes and with two axial phenyl groups in the diorganotin complexes. The ligands are coordinated through N and 0 or S and ONO or ONS donar sites. © 1990, Taylor & Francis Group, LLC. All rights reserved.
Citation: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry(1990), 20(5): 623-643
URI: https://doi.org/10.1080/00945719008048160
http://repository.iitr.ac.in/handle/123456789/3692
Issue Date: 1990
ISSN: 945714
Author Scopus IDs: 7103033909
57205972230
7202115093
Author Affiliations: Nath, M., Department of Chemistry, University of Roorkee, ROORKEE, 247 667, India
Sharma, N., Department of Chemistry, University of Roorkee, ROORKEE, 247 667, India
Sharma, C.L., Department of Chemistry, University of Roorkee, ROORKEE, 247 667, India
Funding Details: The authors are highly thankful to the Head of the Chemistry Department, U .O .R . , Roorkee , for providing laboratory facilities. Thanks are also due to Prof. R.P. Ghandhi (I.I.T, New Delhi) for ‘HNMR spectra and to Dr. A.K. Singh (I,I.T., New Delhi) for microanalyses and far 1.K. spectra and Dr. Bhargava (B.A.R.C., Bombay) for recording the M6ssbauer spectra of one compound. One of the authors (N.S.) gratefully acknowledges U.P.C.S.T., Lucknow, for awarding a Junior Research Fellowship.
Appears in Collections:Journal Publications [CY]

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