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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3690
Title: Synthesis and structural features of s-benzyldithiocarbazate schiff base complexes of organotin(iv)
Authors: Nath, Mala
Sharma N.
Sharma C.L.
Published in: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Abstract: The organotin (IV) complexes with Schiff bases derived from aromatic aldehydes/ketones and S-benzyldithiocarbazate, such as S-benzyl- β -N-(2-hydroxyphenyl)methylendithiocarba - zate(H2L-1), S-benzyl - β -N-(2-hydroxy-1-paphthyl)methylendithiocarbazate(H2L-2), S-benzyl- β -N-(2-hydroxyphenylethylidene)-dithiocarbazate(H2L-3), S-benzyl—β —N-(2-methoxyphenyl)methylendithiocarbazate(HL-4), S-benzyl—β—N-(4-methoxyphenyl)methylendithiocarbazate(HL-5), S-benzyl—β—N-(2-furanyl)methylendithiocarbazate(HL-6) S-benzyl— β—N-(benzoylphenyl)methylendithiocarbazate(HL-7), of the general RnSnL (where n = 2, R = C6H5, L = dibasic thio-Schiff base, H2L-1, H2L-2 and H2L-3; n = 3, R = CH3 or C6H6, L = monobasic thio-Schiff base, HL-4, HL-5, HL-6 and HL-7)have been prepared and characterized on the basis of elemental analyses, conductivity measurements and infrared, far-infrared, electronic and nuclear magnetic resonance spectral studies. Infrared spectral studies indicate that thio-Schiff bases behave as bidentate (NS) or tridentate(ONS) ligands and form rings through the thiol sulphur, the azomethine nitrogen and the phenolic oxygen. On the basis of the spectral data a distorted trigonal bipyramidal geometry around the tin atom is suggested for the complexes. © 1990, Taylor & Francis Group, LLC. All rights reserved.
Citation: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry(1990), 20(10): 1355-1372
URI: https://doi.org/10.1080/00945719008048639
http://repository.iitr.ac.in/handle/123456789/3690
Issue Date: 1990
ISSN: 945714
Author Scopus IDs: 7103033909
57205972230
7202115093
Author Affiliations: Nath, M., Department of Chemistry, University of Roorkee, Koorkee, 247 667, India
Sharma, N., Department of Chemistry, University of Roorkee, Koorkee, 247 667, India
Sharma, C.L., Department of Chemistry, University of Roorkee, Koorkee, 247 667, India
Funding Details: The authors are thankful to the Head of the Chemistry Department, University of Roorkee, Roorkee, for providing labo- ratory facilities and the Head of the Chemistry Department of the Indian institute of Technology, New Delhi, for providing the facilities for microanalyses, far-IR and PMR spectra. The authors are grateful to U.P.C.S.T., Lucknow for financial assistance.
Appears in Collections:Journal Publications [CY]

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