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dc.contributor.authorChahal M.K.-
dc.contributor.authorSankar, Muniappan-
dc.contributor.authorButcher R.J.-
dc.date.accessioned2020-10-06T14:27:26Z-
dc.date.available2020-10-06T14:27:26Z-
dc.date.issued2017-
dc.identifier.citationPhysical Chemistry Chemical Physics (2017), 19(6): 4530-4540-
dc.identifier.issn14639076-
dc.identifier.urihttps://doi.org/10.1039/c6cp08396j-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/3576-
dc.description.abstractThe synthesis of three new classes of mixed β-pyrrole substituted tetraphenylporphyrins, MTPP(R), MTPP(Br)2(R) (where R = -CHC(CN)2, -CHC(CN)(COOC2H5), -CH(CN)(COOH) and M = 2H, Ni(ii), Cu(ii)) and MTPP(NO2)(Ph-p-R′)2 (R′ = -CHO and -CHC(CN)2 and M = 2H, Ni(ii), Cu(ii)) have been reported. The crystal structures of CuTPP(Br)2-ECA (7a), NiTPP(NO2)(Ph-p-CHO)2 (9) and NiTPP(NO2)(Ph-p-CH(CN)2)2 (10) are highly nonplanar among β-trisubstituted porphyrins reported to date as evidenced from the mean displacement of β-pyrrole carbon (ΔCβ) in the range ±(0.39-0.674) Å. The olefin mediated ethyl cyanoacetate is in plane with the porphyrin core in CuTPP(Br)2-ECA (the dihedral angle relative to the pyrrole NC4-mean plane is 39.81°) while dicyanovinyl stays aside for NiTPP(NO2)(Ph-p-CH(CN)2)2 (dihedral angles relative to the pyrrole NC4-mean plane are 75.03° and 67.47°). NiTPP-MN (2), NiTPP-ECA (3), NiTPP(Br)2-MN (6) and NiTPP(Br)2-ECA (7) act as chemodosimeters for toxic CN- ions whereas NiTPP-CAA (4) and NiTPP(Br)2-CAA (8) act as chemosensors to detect toxic ions such as CN-, F- and OAc- depending on the acceptor strength and an obstacle in the conjugation pathway. The dicyanovinyl group in the phenyl olefinic-mediated porphyrin NiTPP(NO2)(Ph-p-CH(CN)2)2 (10) also acts as chemodosimeter for CN- ions but no vivid changes are observed via different spectroscopic methods. © the Owner Societies 2017.-
dc.language.isoen_US-
dc.publisherRoyal Society of Chemistry-
dc.relation.ispartofPhysical Chemistry Chemical Physics-
dc.titleAn insight into the communication between β-olefin/phenyl olefin-mediated acceptors and porphyrin π-system: A way to establish porphyrin based chemodosimeters and chemosensors-
dc.typeArticle-
dc.scopusid55696261900-
dc.scopusid6701530390-
dc.scopusid7201947292-
dc.affiliationChahal, M.K., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247667, India-
dc.affiliationSankar, M., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247667, India-
dc.affiliationButcher, R.J., Department of Chemistry, Howard University, Washington, DC 20059, United States-
dc.description.fundingWe sincerely thank the Science and Engineering Research Board (SB/FT/CS-015/2012), the Board of Research in Nuclear Science (2012/37C/61/BRNS) and the Council of Scientific and Industrial Research (01(2694)/12/EMR-II) for financial support. MKC thanks the University Grants Commission (UGC), India for senior research fellowship.-
dc.description.correspondingauthorSankar, M.; Department of Chemistry, Indian Institute of Technology RoorkeeIndia; email: sankafcy@iitr.ac.in-
Appears in Collections:Journal Publications [CY]

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