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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3481
Title: Ruthenium(II) complexes derived from the ligands having carboxamide groups: Reactivity and scavenging of nitric oxide (NO) Dedicated to Professor R. N. Mukherjee on his 60th birthday.
Authors: Ghosh, Kaushik
Kumar S.
Kumar R.
Singh U.P.
Published in: Journal of Organometallic Chemistry
Abstract: Two novel ruthenium(II) complexes [RuII(L1)(PPh 3)2(CO)] (1) and [RuII(L3)(PPh 3)2(DMF)] (2) derived from the carboxamide ligands L 1H2 and L2H2 respectively (where L1H2 = N2,N6-dip-tolylpyridine-2,6- dicarboxamide and L2H2 = N2,N 6-di(naphthalen-1-yl)pyridine-2,6-dicarboxamide) were synthesized and characterized. Molecular structures of complexes 1·CH3OH and 2·DMF were authenticated using X-ray crystallographic studies. Both the complexes were characterized using IR, UV-vis, elemental analysis, NMR and ESI-mass spectral studies. Electrochemical studies were performed to investigate the redox properties. Nitric oxide (NO) scavenging activity of these complexes was also observed with the help of Griess reagent reaction. © 2013 Elsevier B.V. All rights reserved.
Citation: Journal of Organometallic Chemistry (2014), 750(): 169-175
URI: https://doi.org/10.1016/j.jorganchem.2013.10.054
http://repository.iitr.ac.in/handle/123456789/3481
Issue Date: 2014
Keywords: Carboxamide group
Metal redox
Nitric oxide (NO)
NO scavenging
Ruthenium complex
ISSN: 0022328X
Author Scopus IDs: 57204513823
7405769266
57208685185
57203181883
Author Affiliations: Ghosh, K., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247667, Uttarakhand, India
Kumar, S., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247667, Uttarakhand, India
Kumar, R., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247667, Uttarakhand, India
Singh, U.P., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247667, Uttarakhand, India
Funding Details: KG is thankful to CSIR , India for financial assistance No. 01(2720)/13/EMR-II dated 17-APRIL-2013). SK and RK are thankful to CSIR for financial support. Appendix A
Corresponding Author: Ghosh, K.; Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee 247667, Uttarakhand, India; email: ghoshfcy@iitr.ernet.in
Appears in Collections:Journal Publications [CY]

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