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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3467
Title: Orthometallation in bidentate Schiff base ligands via C-H activation: Synthesis of ruthenium(III) organometallic complexes
Authors: Ghosh, Kaushik
Kumar R.
Kumar S.
Bala M.
Singh U.P.
Published in: Transition Metal Chemistry
Abstract: Schiff bases obtained by the reactions of substituted aromatic aldehydes with phenyl hydrazine or 2,4-dinitrophenyl hydrazine were synthesized and characterized by spectroscopic methods. Cyclometalated Ru(III) complexes of general formula, namely [Ru(L)(PPh3)2Cl], were synthesized from the Schiff bases via C-H bond activation and characterized by spectroscopic and electrochemical studies. In addition, one molecular structure of one of the complexes was determined by X-ray crystallography. The redox behavior of the complexes was examined by electrochemical studies, and one mechanism of orthometallation was investigated. © 2015 Springer International Publishing Switzerland.
Citation: Transition Metal Chemistry (2015), 40(8): 831-837
URI: https://doi.org/10.1007/s11243-015-9979-1
http://repository.iitr.ac.in/handle/123456789/3467
Issue Date: 2015
Publisher: Kluwer Academic Publishers
ISSN: 3404285
Author Scopus IDs: 57204513823
57208685185
7405769266
56844899900
57203181883
Author Affiliations: Ghosh, K., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India
Kumar, R., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India
Kumar, S., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India
Bala, M., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India
Singh, U.P., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India
Corresponding Author: Ghosh, K.; Department of Chemistry, Indian Institute of Technology, RoorkeeIndia
Appears in Collections:Journal Publications [CY]

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