http://repository.iitr.ac.in/handle/123456789/3467| Title: | Orthometallation in bidentate Schiff base ligands via C-H activation: Synthesis of ruthenium(III) organometallic complexes |
| Authors: | Ghosh, Kaushik Kumar R. Kumar S. Bala M. Singh U.P. |
| Published in: | Transition Metal Chemistry |
| Abstract: | Schiff bases obtained by the reactions of substituted aromatic aldehydes with phenyl hydrazine or 2,4-dinitrophenyl hydrazine were synthesized and characterized by spectroscopic methods. Cyclometalated Ru(III) complexes of general formula, namely [Ru(L)(PPh3)2Cl], were synthesized from the Schiff bases via C-H bond activation and characterized by spectroscopic and electrochemical studies. In addition, one molecular structure of one of the complexes was determined by X-ray crystallography. The redox behavior of the complexes was examined by electrochemical studies, and one mechanism of orthometallation was investigated. © 2015 Springer International Publishing Switzerland. |
| Citation: | Transition Metal Chemistry (2015), 40(8): 831-837 |
| URI: | https://doi.org/10.1007/s11243-015-9979-1 http://repository.iitr.ac.in/handle/123456789/3467 |
| Issue Date: | 2015 |
| Publisher: | Kluwer Academic Publishers |
| ISSN: | 3404285 |
| Author Scopus IDs: | 57204513823 57208685185 7405769266 56844899900 57203181883 |
| Author Affiliations: | Ghosh, K., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India Kumar, R., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India Kumar, S., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India Bala, M., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India Singh, U.P., Department of Chemistry, Indian Institute of Technology, Roorkee, Roorkee, Uttarakhand, 247667, India |
| Corresponding Author: | Ghosh, K.; Department of Chemistry, Indian Institute of Technology, RoorkeeIndia |
| Appears in Collections: | Journal Publications [CY] |
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