http://repository.iitr.ac.in/handle/123456789/3426| Title: | Copper(II) and cobalt(II) complexes of 2,2-diphenyl-4,4,6,6-tetrakis(1-pyrazolyl) cyclotriphosphazene, N3P3Ph2Pz4. X-ray crystal structure of N3P3Ph2Pz4·CoCl2·0.5CH2Cl2 |
| Authors: | Justin Thomas, K. R. Chandrasekhar V. Scott S.R. Cordes A.W. |
| Published in: | Polyhedron |
| Abstract: | Synthesis and characterization of isotypical compounds N3P3Ph2Pz4·MX2 (M = Cu, X = Cl or Br; M = Co, X = Cl) are reported. The X-ray crystal structure of N3P3Ph2Pz4·CoCl2·0.5CH2Cl2 is described. The structure is a distorted trigonal bipyramid in which the cobalt atom is coordinated by a ligand molecule through the two nongeminal pyrazolyl pyridinic nitrogens at the equatorial sites and a cyclophosphazene ring nitrogen at the axial position. The remaining axial and equatorial positions are occupied by the two chlorine atoms. © 1995. |
| Citation: | Polyhedron (1995), 14(12): 1607-1613 |
| URI: | https://doi.org/10.1016/0277-5387(94)00434-G http://repository.iitr.ac.in/handle/123456789/3426 |
| Issue Date: | 1995 |
| ISSN: | 2775387 |
| Author Scopus IDs: | 57203389297 7006003609 15075424800 7006516385 |
| Author Affiliations: | Justin Thomas, K.R., Department of Chemistry, Indian Institute of Technology, Kanpur, 208 016, India Chandrasekhar, V., Department of Chemistry, Indian Institute of Technology, Kanpur, 208 016, India Scott, S.R., Department of Chemistry and Biochemistry, Fulbright College of Arts and Sciences, University of Arkansas, Feyetteville, AK 72701-1201, United States Cordes, A.W., Department of Chemistry and Biochemistry, Fulbright College of Arts and Sciences, University of Arkansas, Feyetteville, AK 72701-1201, United States |
| Corresponding Author: | Chandrasekhar, V.; Department of Chemistry, Indian Institute of Technology, Kanpur, 208 016, India |
| Appears in Collections: | Journal Publications [CY] |
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