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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3416
Title: Ferrocene end-capped palladium(II) and platinum(II) complexes with thiophene spacers
Authors: Thomas K.R.J.
Lin J.T.
Lin K.-J.
Published in: Organometallics
Abstract: A series of heterobimetallics containing ferrocene and Pd(II) or Pt(II) have been synthesized by oxidative addition of ferrocene-substituted halothiophenes with zerovalent palladium or platinum precursors. The stable solids were thoroughly characterized by elemental analysis, NMR, UV-vis spectroscopy, and cyclic voltammetry. The rich redox chemistry of the complexes depends on the conjugation length that separates the two metal sites. The crystal structure of a platinum σ-thienyl complex, (C5H5)Fe(C5H4CH=CH-th-Pt(PPh 3)2(Br)) (th = 2,5-disubstituted thiophene) has been determined.
Citation: Organometallics (1999), 18(25): 5285-5291
URI: http://repository.iitr.ac.in/handle/123456789/3416
Issue Date: 1999
ISSN: 2767333
Author Scopus IDs: 57203389297
7501725859
7403967959
Author Affiliations: Thomas, K.R.J., Institute of Chemistry, Academia Sinica, 115, Taipei, Taiwan
Lin, J.T., Institute of Chemistry, Academia Sinica, 115, Taipei, Taiwan
Lin, K.-J., Institute of Chemistry, Academia Sinica, 115, Taipei, Taiwan
Corresponding Author: Lin, J.T.; Institute of Chemistry, Academia Sinica, 115, Taipei, Taiwan; email: jtlin@chem.sinica.edu.tw
Appears in Collections:Journal Publications [CY]

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