http://repository.iitr.ac.in/handle/123456789/3353
Title: | N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1, 3-benzothiadiazol-4-amine |
Authors: | Bolisetty M.N.K.P. Justin Thomas, K. R. Ng S.W. Tiekink E.R.T. |
Published in: | Acta Crystallographica Section E: Structure Reports Online |
Abstract: | In the title compound, C 30H 34N 4S, each of the benzothia-diazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the molecule. Each of the benzothiadiazole ring N atoms forms a significant intramolecular contact, i.e. N - H⋯N or C - H⋯N. In the crystal, linear supra-molecular chains along the c axis are generated by C - H⋯N interactions involving the tertiary amine N atom. |
Citation: | Acta Crystallographica Section E: Structure Reports Online (2012), 68(3): o911-o912 |
URI: | https://doi.org/10.1107/S1600536812008239 http://repository.iitr.ac.in/handle/123456789/3353 |
Issue Date: | 2012 |
Keywords: | data-to-parameter ratio = 17.1 mean σ(C-C) = 0.002 Å R factor = 0.038 single-crystal X-ray study T = 100 K wR factor = 0.106 |
ISSN: | 16005368 |
Author Scopus IDs: | 55069391900 57203389297 55548511500 55738821800 |
Author Affiliations: | Bolisetty, M.N.K.P., Organic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India Thomas, K.R.J., Organic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India Ng, S.W., Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, Chemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203, Jeddah, Saudi Arabia Tiekink, E.R.T., Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia |
Corresponding Author: | Tiekink, E.R.T.; Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia; email: edward.tiekink@gmail.com |
Appears in Collections: | Journal Publications [CY] |
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