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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3326
Title: Selective naked-eye cyanide detection in aqueous media using a carbazole-derived fluorescent dye
Authors: Konidena R.K.
Thomas K.R.J.
Published in: RSC Advances
Abstract: A Michael addition activated chemodosimeter was designed with a carbazole donor and a dicyanovinyl acceptor. The design features an acceptor-donor- acceptor (A-D-A) molecular configuration and the cyanide addition on the electron-deficient alkene bridge breaks the donor-acceptor interaction and produces a blue shift in the absorption and emission profiles. The ratiometric and colorimetric changes of the probes were monitored by the changes in absorption and fluorescence spectra. The probes exhibited excellent selectivity towards CN- over other anions such as F-, OAc-, NO3-, NO2-, S2O 3-, H2PO4-, SCN -, I-, Br-, and SO4-. The action of the chemodosimeter was investigated by 1H-NMR titrations and DFT/TDDFT theoretical calculations which supported the formation of dicyanide addition adducts (CN-probes-CN)-2 with the probes. Paper strips developed using the dyes displayed excellent response for the detection of CN- in aqueous solutions. The detection limits of the probes 3a (0.126 μM) and 3b (0.140 μM) for cyanide are lower than the maximum permissible level of CN- (1.9 μM) in drinking water. © 2014 the Partner Organisations.
Citation: RSC Advances (2014), 4(44): 22902-22910
URI: https://doi.org/10.1039/c4ra02636e
http://repository.iitr.ac.in/handle/123456789/3326
Issue Date: 2014
Publisher: Royal Society of Chemistry
ISSN: 20462069
Author Scopus IDs: 56200880700
57203389297
Author Affiliations: Konidena, R.K., Organic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India
Thomas, K.R.J., Organic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India
Corresponding Author: Thomas, K.R.J.; Organic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, India; email: krjt8fcy@iitr.ac.in
Appears in Collections:Journal Publications [CY]

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