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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3068
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dc.contributor.authorGnanamani, Elumalai-
dc.contributor.authorSomeshwar N.-
dc.contributor.authorRamanathan C.R.-
dc.date.accessioned2020-10-06T14:25:38Z-
dc.date.available2020-10-06T14:25:38Z-
dc.date.issued2012-
dc.identifier.citationAdvanced Synthesis and Catalysis (2012), 354(44176): 2101-2106-
dc.identifier.issn16154150-
dc.identifier.urihttps://doi.org/10.1002/adsc.201200115-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/3068-
dc.description.abstractA pyridine unit with a conformationally rigid chiral backbone has been designed and synthesized in an enantiomerically pure form to utilize in the Lewis base-catalyzed Sakurai-Hosomi-Denmark-type allylation reaction. The chiral pyridine N-oxide in 1:1 mixture of chloroform and 1,1,2,2-tetrachloroethane produced the homoallylic alcohols in up to 98% yield and up to 94% ee. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.language.isoen_US-
dc.relation.ispartofAdvanced Synthesis and Catalysis-
dc.subjectactivation of allylsilanes-
dc.subjectcatalyst design-
dc.subjectchiral pyridine N-oxides-
dc.subjecthomoallylic alcohols.-
dc.subjectorganocatalysts-
dc.titleConformationally rigid chiral pyridine N-oxides as organocatalyst: Asymmetric allylation of aldehydes-
dc.typeArticle-
dc.scopusid35319775800-
dc.scopusid55336233600-
dc.scopusid7003576480-
dc.affiliationGnanamani, E., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India-
dc.affiliationSomeshwar, N., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India-
dc.affiliationRamanathan, C.R., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India-
dc.description.correspondingauthorRamanathan, C.R.; Department of Chemistry, Pondicherry University, Puducherry - 605 014, India; email: crrnath.che@pondiuni.edu.in-
Appears in Collections:Journal Publications [CY]

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