http://repository.iitr.ac.in/handle/123456789/3068| Title: | Conformationally rigid chiral pyridine N-oxides as organocatalyst: Asymmetric allylation of aldehydes |
| Authors: | Gnanamani, Elumalai Someshwar N. Ramanathan C.R. |
| Published in: | Advanced Synthesis and Catalysis |
| Abstract: | A pyridine unit with a conformationally rigid chiral backbone has been designed and synthesized in an enantiomerically pure form to utilize in the Lewis base-catalyzed Sakurai-Hosomi-Denmark-type allylation reaction. The chiral pyridine N-oxide in 1:1 mixture of chloroform and 1,1,2,2-tetrachloroethane produced the homoallylic alcohols in up to 98% yield and up to 94% ee. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Citation: | Advanced Synthesis and Catalysis (2012), 354(44176): 2101-2106 |
| URI: | https://doi.org/10.1002/adsc.201200115 http://repository.iitr.ac.in/handle/123456789/3068 |
| Issue Date: | 2012 |
| Keywords: | activation of allylsilanes catalyst design chiral pyridine N-oxides homoallylic alcohols. organocatalysts |
| ISSN: | 16154150 |
| Author Scopus IDs: | 35319775800 55336233600 7003576480 |
| Author Affiliations: | Gnanamani, E., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India Someshwar, N., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India Ramanathan, C.R., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India |
| Corresponding Author: | Ramanathan, C.R.; Department of Chemistry, Pondicherry University, Puducherry - 605 014, India; email: crrnath.che@pondiuni.edu.in |
| Appears in Collections: | Journal Publications [CY] |
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