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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/3068
Title: Conformationally rigid chiral pyridine N-oxides as organocatalyst: Asymmetric allylation of aldehydes
Authors: Gnanamani, Elumalai
Someshwar N.
Ramanathan C.R.
Published in: Advanced Synthesis and Catalysis
Abstract: A pyridine unit with a conformationally rigid chiral backbone has been designed and synthesized in an enantiomerically pure form to utilize in the Lewis base-catalyzed Sakurai-Hosomi-Denmark-type allylation reaction. The chiral pyridine N-oxide in 1:1 mixture of chloroform and 1,1,2,2-tetrachloroethane produced the homoallylic alcohols in up to 98% yield and up to 94% ee. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Citation: Advanced Synthesis and Catalysis (2012), 354(44176): 2101-2106
URI: https://doi.org/10.1002/adsc.201200115
http://repository.iitr.ac.in/handle/123456789/3068
Issue Date: 2012
Keywords: activation of allylsilanes
catalyst design
chiral pyridine N-oxides
homoallylic alcohols.
organocatalysts
ISSN: 16154150
Author Scopus IDs: 35319775800
55336233600
7003576480
Author Affiliations: Gnanamani, E., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India
Someshwar, N., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India
Ramanathan, C.R., Department of Chemistry, Pondicherry University, Puducherry - 605 014, India
Corresponding Author: Ramanathan, C.R.; Department of Chemistry, Pondicherry University, Puducherry - 605 014, India; email: crrnath.che@pondiuni.edu.in
Appears in Collections:Journal Publications [CY]

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