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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/25289
Title: Novel cyanonitrosyl complexes of chromium(I) with aniline and substituted anilines
Authors: Maurya R.C.
Shukla R.
Shukla R.K.
Anandam N.
Gupta D.C.
Maurya, Mannar Ram
Published in: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Abstract: A new series of mixed cyanonitrosyl complexes of chromiun(1) having octahedral stereochemistry around the Cr ion with the general formula [CrNO(CN)2L2(H2O)] (where L= o-, m- and p-toluidines, o-, m- and p- chloroanilines, o- and p- bromoani-lines or 5- fluoro- 2- methyl aniline) has been isolated in solid state by the interaction of potassium pentacyanonitrosylchromate(I) monohydrate with the said ligands. The complexes have been characterised by elemental analyses, electrical conductance, magnetic measurement, molecular weight determination, electron spin resonance, and infrared spectral studies. Chromium(I) has a low- spin d5 configuration in these complexes. © 1986, Taylor & Francis Group, LLC. All rights reserved.
Citation: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 16(8): 1059-1066
URI: https://doi.org/10.1080/00945718608071381
http://repository.iitr.ac.in/handle/123456789/25289
Issue Date: 1986
ISSN: 945714
Author Scopus IDs: 7004649231
7202274153
57198167772
16457035600
56235854600
7005255411
Author Affiliations: Maurya, R.C., Department of Chemistry, Atarra P. G. College, Atarra- 210201, India
Shukla, R., Department of Chemistry, Atarra P. G. College, Atarra- 210201, India
Shukla, R.K., Department of Chemistry, Atarra P. G. College, Atarra- 210201, India
Anandam, N., Department of Chemistry, Atarra P. G. College, Atarra- 210201, India
Gupta, D.C., Department of Chemistry, Atarra P. G. College, Atarra- 210201, India
Maurya, M.R., Department of Chemistry, Regional Engineering College, Kurukshetra- 132119, India
Funding Details: 
Appears in Collections:Journal Publications [CY]

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