http://repository.iitr.ac.in/handle/123456789/25279| Title: | New dioxouranium(VI) complexes of tridentate schiff bases derived from 2-cresotic acid hydrazide and various aldehydes/ketones |
| Authors: | Maurya, Mannar Ram Singh D.P. Verma S.K. |
| Published in: | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry |
| Abstract: | Six new dioxouranium(VI) complexes of the type trans-UCHL-CHgOH. where LH2 «= a Schiff base derived from Q-cresotic acid hydrazide and salicylaldehyde, 5-chlorosalicylaldehyde, 2-hydroxyl-naphthaldehyde, a-hydroxyacetophenone, g-hydroxybenzophenone and pyridoxal, have been synthesized and characterized on the basis of elemental analysis, molecular weight, conductance, magnetic susceptibility, IR, NMR and electronic spectral measurements. The complexes are non-electrolytes, monomers, diamagnetic and six-coordinated. The Schiff bases behave as dibasic tridentate ligands and coordinate through the phenolic oxygen, azomethine nitrogen and enolic oxygen atoms. The complexes have a trans-Q=U=Q structure and show a strong and broad band at 21000–23000 cm”- due to the l£+g-> transition. © 1989, Taylor & Francis Group, LLC. All rights reserved. |
| Citation: | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 19(9): 923-930 |
| URI: | https://doi.org/10.1080/00945718908050644 http://repository.iitr.ac.in/handle/123456789/25279 |
| Issue Date: | 1989 |
| ISSN: | 945714 |
| Author Scopus IDs: | 7005255411 35323312100 56966890400 |
| Author Affiliations: | Maurya, M.R., Department of Chemistry, Iowa State University, 43 Gilman Hall, Ames, Iowa 50011, United States Singh, D.P., Department of Chemistry, Regional Engineering College, Kurukshetra 132 119, Haryana, India Verma, S.K., Department of Chemistry, Regional Engineering College, Kurukshetra 132 119, Haryana, India |
| Funding Details: | |
| Appears in Collections: | Journal Publications [CY] |
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