http://repository.iitr.ac.in/handle/123456789/25278| Title: | Synthesis and characterization of a new bis-alanyl-appended porphyrin and its mononuclear Cu(II), Ni(II) and Zn(II) complexes. Crystal structure of the Ni(II) complex |
| Authors: | Woo L.K. Maurya, Mannar Ram Tolppi C.J. Jacobson R.A. Shumei Y. Rose E. |
| Published in: | Inorganica Chimica Acta |
| Abstract: | A new multi-chelating ligand, cis-5,15-bis(o-[β-alanylamido]phenyl)-2,8,12,18-tetraethyl-3,7,13,1 7-tetramethylporphyrin, cis-(ala)2DPE, has been synthesized. Treatment of cis-(ala)2DPE with methanol solutions of Ni(II), Cu(II) or Zn(II) leads to the formation of mononuclear metal complexes in which the metal has inserted into the porphyrin core. An X-ray structure determination was carried out for [cis- (ala)2DPE]Ni(II)·CHCl3·CH3OH. Crystal data are as follows: monoclinic, P21/n, a=14.195(5), b=12.175(6), c=28.071(1) Å, β=98.97(3)°, R=0.085, Rw=0.089. © 1991. |
| Citation: | Inorganica Chimica Acta, 182(1): 41-48 |
| URI: | https://doi.org/10.1016/S0020-1693(00)85184-1 http://repository.iitr.ac.in/handle/123456789/25278 |
| Issue Date: | 1991 |
| ISSN: | 201693 |
| Author Scopus IDs: | 7102911730 7005255411 24757160500 7201670683 24757128600 36080187300 |
| Author Affiliations: | Woo, L.K., Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States Maurya, M.R., Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States Tolppi, C.J., Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States Jacobson, R.A., Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States Shumei, Y., Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States Rose, E., Universiteé Pierre et Marie Curie, Laboratoire de Chimie Organique, UA 408, 4 Place Jussieu, 75230 Paris Cédex 05 France |
| Funding Details: | We thank Jenny Evans Liras, Peter Langr, Ann Marie Dockstadter, Diana Hoganson and John Tolppi for synthesizing porphyrin precursors. Financial support for this work was provided by the USDOE through the Ames Laboratory. U.S. Department of Energy, USDOE; Ames Laboratory, AL |
| Corresponding Author: | Woo, L.K.; Ames Laboratory, Department of Chemistry, Iowa State University, Ames, IA 50011, United States |
| Appears in Collections: | Journal Publications [CY] |
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