http://repository.iitr.ac.in/handle/123456789/25273| Title: | Reactivity of bis(acetylacetonato)dinitrosylmolybdenum(0) towards schiff bases derived from salicylaldehyde or o-vanillin and benzoylhydrazide, or isonicotinoylhydrazide |
| Authors: | Maurya, Mannar Ram Gopinathan S. Gopinathan C. Maurya R.C. |
| Published in: | Polyhedron |
| Abstract: | The synthesis of dinitrosylmolybdenum(0) complexes of Schiff bases by a single-step ligand-exchange process has been reported for the first time by the reaction of [Mo(NO)2(acac)2] with the Schiff bases (LH2) obtained by the condensation of salicylaldehyde or o-vanillin and benzoylhydrazide, or isonicotinoylhydrazide, and are of the type [Mo(NO)2(LH)2]. The Schiff behave as monobasic bidentate ligands coordinating through the azomethine nitrogen and enolic oxygen after deprotonation. Two geometric isomers having nitrosyl trans to each other have been observed in solution. Another complex, [MoO2(sal-INH) · MeOH], has also been synthesized for comparison. © 1993. |
| Citation: | Polyhedron, 12(2): 159-163 |
| URI: | https://doi.org/10.1016/S0277-5387(00)81622-8 http://repository.iitr.ac.in/handle/123456789/25273 |
| Issue Date: | 1993 |
| ISSN: | 2775387 |
| Author Scopus IDs: | 7005255411 7003620515 7003768353 7004649231 |
| Author Affiliations: | Maurya, M.R., Inorganic Chemistry Division, National Chemical Laboratory, Pune, 411 008, India Gopinathan, S., Inorganic Chemistry Division, National Chemical Laboratory, Pune, 411 008, India Gopinathan, C., Inorganic Chemistry Division, National Chemical Laboratory, Pune, 411 008, India Maurya, R.C., Department of Chemistry, R.D. University, Jabalpur, M.P. 482 001, India |
| Funding Details: | |
| Corresponding Author: | Maurya, M.R.; Inorganic Chemistry Division, National Chemical Laboratory, Pune, 411 008, India |
| Appears in Collections: | Journal Publications [CY] |
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