http://repository.iitr.ac.in/handle/123456789/25264| Title: | Ruthenium(II) hydrido complexes of S-methyldithiocarbazates |
| Authors: | Maurya, Mannar Ram Unny I.R. Alekar N.A. Gopinathan S. Gopinathan C. |
| Published in: | Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry |
| Abstract: | Reactions of [RuHCl(CO)(PPh3)3] and [RuH2(CO)(PPh3)3] with schiff bases (HL) derived from S-methyldithiocarbazate and pyridine-2-aldehyde, 2-acetylpyridine, thiophene-2-aldehyde, 2- acetylthiophene and furan-2-aldehyde lead to the formation of neutral complexes of the type [RuX(CO)(PPh3)2L] (X = H or Cl). The probable stereochemistries of the complexes have been established on the basis of elemental analysis, IR, 1H and 13C NMR studies. The triphenylphosphines are trans leaving CO and H or Cl cis to each other in the complexes. |
| Citation: | Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 36(12): 1058-1062 |
| URI: | https://doi.org/ http://repository.iitr.ac.in/handle/123456789/25264 |
| Issue Date: | 1997 |
| ISSN: | 3764710 |
| Author Scopus IDs: | 7005255411 6506508979 6506744682 7003620515 7003768353 |
| Author Affiliations: | Maurya, M.R., Inorganic Chemistry Division, National Chemical Laboratory, Pune 411 008, India, Department of Chemistry, University of Roorkee, Roorkee 247 667, India Unny, I.R., Inorganic Chemistry Division, National Chemical Laboratory, Pune 411 008, India Alekar, N.A., Inorganic Chemistry Division, National Chemical Laboratory, Pune 411 008, India Gopinathan, S., Inorganic Chemistry Division, National Chemical Laboratory, Pune 411 008, India Gopinathan, C., Inorganic Chemistry Division, National Chemical Laboratory, Pune 411 008, India |
| Funding Details: | |
| Corresponding Author: | Gopinathan, S.; Inorganic Chemistry Division, , Pune 411 008, India |
| Appears in Collections: | Journal Publications [CY] |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.