Zeolite-encapsulated Cr(III), Fe(III), Ni(II), Zn(II) and Bi(III) salpn complexes as catalysts for the decomposition of H2O2 and oxidation of phenol

Abstract

Cr(III), Fe(III), Bi(III), Ni(II) and Zn(II) complexes of N,N′-bis(salicylidene)propane-1,3-diamine (H2 salpn) encapsulated in Y-zeolite were prepared by flexible ligand method. These complexes were characterized by chemical and thermal analyses, FT-IR and electronic spectral studies and their XRD pattern. The encapsulated materials are active catalysts for the decomposition of hydrogen peroxide and for the oxidation of phenol using H2O2 as oxidant with good selectivity. © 2002 Published by Elsevier Science B.V.