Skip navigation
Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/25160
Title: Co-processing of bio-oil from de-oiled Jatropha curcas seed cake with refinery gas-oil over sulfided CoMoP/Al2O3 catalyst
Authors: Poddar M.K.
Rai A.
Maurya, Mannar Ram
Sinha A.K.
Published in: RSC Advances
Abstract: A sulfided cobalt-molybdenum-phosphorus/aluminium oxide (CoMoP/Al2O3) catalyst was studied in the hydroprocessing of bio-oil (BO) obtained from the pyrolysis of de-oiled Jatropha curcas seed cake. Hydroprocessing was carried out with different ratios of refinery gas oil (GO) and BO. The oxygen content in the products was reduced to trace amounts after hydroprocessing. A clear product obtained from the co-processing of BO with refinery GO contained 2-16% gasoline, 30-35% kerosene, 35-44% diesel, with 50-60% alkanes, 10-45% cycloalkanes, and 1-10% aromatics, with a negligible amount of char formed in the process. Hydroprocessing of 100% BO produced 30% kerosene and 30% diesel, together with 10% gasoline, with 15% of alkanes and 15% cycloalkanes, and 45% aromatics. A maximum amount of kerosene (41%) was obtained at 648 K and 75 bar from 100% BO, with a small amount of char (1.5%) deposited on the catalyst. In comparison, over sulfided CoMo/Al2O3 catalyst (without P promoter) only 31% of kerosene was produced, with 17% char, using similar reaction conditions. © The Royal Society of Chemistry
Citation: RSC Advances, 6(114): 113720-113726
URI: https://doi.org/10.1039/c6ra20893b
http://repository.iitr.ac.in/handle/123456789/25160
Issue Date: 2016
Publisher: Royal Society of Chemistry
Keywords: Biofuels
Catalysts
Gas oils
Gasoline
Kerosene
Molybdenum oxide
Paraffins
Refining
Cobalt-molybdenum
Cyclo-alkanes
Hydroprocessing
Jatropha curcas
Oxygen content
Reaction conditions
Sulfided CoMo
Trace amounts
Hydrocracking
ISSN: 20462069
Author Scopus IDs: 56196832400
56681749900
7005255411
57213924977
Author Affiliations: Poddar, M.K., CSIR-Indian Institute of Petroleum, Dehradun, India, Indian Institute of Technology, Roorkee, India
Rai, A., CSIR-Indian Institute of Petroleum, Dehradun, India
Maurya, M.R., Indian Institute of Technology, Roorkee, India
Sinha, A.K., CSIR-Indian Institute of Petroleum, Dehradun, India
Funding Details: 
Corresponding Author: Sinha, A.K.; CSIR-Indian Institute of PetroleumIndia; email: asinha@iip.res.in
Appears in Collections:Journal Publications [CY]

Files in This Item:
There are no files associated with this item.
Show full item record


Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.