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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/24669
Title: Isolation of a manganese complex of a tridentate azo-aromatic ligand from an unusual Mn2(CO)10 promoted simultaneous reductive azo cleavage and aromatic ring amination reactions
Authors: Chatterjee S.
Bandyopadhyay, Anasuya
Hung C.-H.
Goswami S.
Published in: Zeitschrift fur Anorganische und Allgemeine Chemie
Abstract: The reaction of Mn2(CO)10 with pap [pap = 2-(phenylazo) pyridine, L1] in boiling n-octane affords a violet complex, [Mn(L2)2] (1, HL2 NH4C 5N=NC6H4N(H)C6H5). This reaction exemplifies an unusual transformation wherein the anionic tridentate ligand (L2)- is formed by the fusion of phenyl imide fragment, originated from the splitting of the -N=N- function of L1, to pendantphenyl ring of the coordinated azo ligand. X-ray structure of the manganese complex is reported. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
Citation: Zeitschrift fur Anorganische und Allgemeine Chemie, 633(44906): 1775-1777
URI: https://doi.org/10.1002/zaac.200700254
http://repository.iitr.ac.in/handle/123456789/24669
Issue Date: 2007
Keywords: Azoaromatic ligand
Crystal structure
Manganese complex
Mn2 (CO)10 promoted reaction
ISSN: 442313
Author Scopus IDs: 55769748540
36999801800
7403166605
7102060926
Author Affiliations: Chatterjee, S., Indian Association for the Cultivation of Science, Department of Inorganic Chemistry, Kolkata, India
Sanyal, A., Indian Association for the Cultivation of Science, Department of Inorganic Chemistry, Kolkata, India
Hung, C.-H., Academia Sinica, Department of Chemistry, Institute of Chemistry, Nankong, Taipei, Taiwan
Goswami, S., Indian Association for the Cultivation of Science, Department of Inorganic Chemistry, Kolkata, India, Departmentof Inorg. Chemistry, Indian Association for the Cultivation of Science, Kolkata-700 032, India
Corresponding Author: Chatterjee, S.; Indian Association for the Cultivation of Science, , Kolkata, India
Appears in Collections:Journal Publications [PE]

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