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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/24188
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dc.contributor.authorSingh S.-
dc.contributor.authorSil, Anjan-
dc.contributor.authorBysakh S.-
dc.date.accessioned2022-03-22T08:23:50Z-
dc.date.available2022-03-22T08:23:50Z-
dc.date.issued2021-
dc.identifier.citationJournal of Electron Spectroscopy and Related Phenomena, 250-
dc.identifier.issn3682048-
dc.identifier.urihttps://doi.org/10.1016/j.elspec.2021.147087-
dc.identifier.urihttp://repository.iitr.ac.in/handle/123456789/24188-
dc.description.abstractThe present work investigates the chemical compatibility of La2NiO4+δ (LN) and La2Mo1.5W0.5O9 (W-LMO) as cathode/electrolyte and NiWO4 (NW)/La2Mo2O9 (LMO) as anode/electrolyte material for solid oxide fuel cell (SOFC) application respectively. The x- ray diffraction (XRD) study of LN/W-LMO shows the existence of five phases viz., La2NiO4+δ, La2Mo1.5W0.5O9, NiWO4, NiO and La1.77Mo1.77O8.001. Whereas, the XRD analysis of NW/LMO shows the formation of NiO, higher order molybdates viz., La5Mo4O14 and La12Mo6O35 as a result of partial Mo reduction. The formation of NiWO4 as a secondary phase in La2NiO4+δ / La2Mo1.5W0.5O9 is a potential anode material which is studied with La2Mo2O9 as anode/electrolyte by x-ray photoelectron spectroscopy (XPS). The XPS analysis of NW/LMO in Ar-H2 atmosphere reveals the partial reduction of Mo to lower oxidation states. The presence of NiWO4 is also verified by Raman spectroscopy with peaks at 698, 778 and 891 cm−1 with the signatures of W-LMO and Mo-O bonding. © 2021 Elsevier B.V.-
dc.language.isoen_US-
dc.publisherElsevier B.V.-
dc.relation.ispartofJournal of Electron Spectroscopy and Related Phenomena-
dc.subjectAr-H2 atmosphere-
dc.subjectLa2NiO4+δ-
dc.subjectNiWO4-
dc.subjectW doped La2Mo2O9-
dc.subjectX- ray photoelectron spectroscopy-
dc.titleCompatibility study of La2NiO4+δ and La2Mo1.5W0.5O9 as electrode-electrolyte material for solid oxide fuel cell-
dc.typeArticle-
dc.scopusid57211208970-
dc.scopusid7003754102-
dc.scopusid6603150324-
dc.affiliationSingh, S., Acoustics Instrumentation and Mechanical Systems Group, CSIR- Central Building Research Institute Roorkee, Roorkee, 247667, India-
dc.affiliationSil, A., Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, Roorkee, 247667, India-
dc.affiliationBysakh, S., Advanced Materials Characterisation Unit, Central Glass and Ceramic Research Institute Kolkata700032, India-
dc.description.fundingOne of authors (Siddharth Singh) is grateful to Director, CSIR-CBRI Roorkee, for providing motivation and support towards this research work.-
dc.description.correspondingauthorSingh, S.; Acoustics Instrumentation and Mechanical Systems Group, India; email: siddharthsingh@cbri.res.in-
Appears in Collections:Journal Publications [MT]

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