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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/20440
Title: Pyrolysis of almond (Prunus amygdalus) shells: Kinetic analysis, modelling, energy assessment and technical feasibility studies
Authors: Rasool T.
Najar I.
Srivastava, Vimal Chandra
Pandey A.
Published in: Bioresource Technology
Abstract: The aim of this work was to study the thermogravimetric analysis through the pyrolysis of almond (Prunus amygdalus) shells for evaluating its potential for bioenergy at different heating rates (10, 25, and 50 K min−1). The activation energy values for the process were of the range of 153.0, 152.02, and 152.73 kJ mol−1 as calculated by Kissenger-Akahira-Sunrose (KAS), Ozawa-Flynn-Wall (OFW) and Starink models respectively. The change in the Gibbs free energy was ~181 kJ mol−1. Diffusion-based reaction, followed by the chemical reaction mechanism,was dominant thermal degradation as envisaged by the Coats-Redfern method. The validation of the experiments was accomplished through the artificial neural network, reiterating its further usage in any conversional studies of biomass. A difference of < 10 kJ mol−1 between the values of activation energy and enthalpy of the degradation reaction indicated favourable product formation. The results offer potential application of almond shells for energy production through pyrolysis. © 2021 Elsevier Ltd
Citation: Bioresource Technology, 337
URI: https://doi.org/10.1016/j.biortech.2021.125466
http://repository.iitr.ac.in/handle/123456789/20440
Issue Date: 2021
Publisher: Elsevier Ltd
Keywords: Artificial neural network
Diffusion
Kinetics
Pyrolysis
Waste biomass
ISSN: 9608524
Author Scopus IDs: 56394290900
57225192198
35565811700
7201771319
Author Affiliations: Rasool, T., Department of Chemical Engineering, National Institute of Technology Srinagar, Srinagar, 190006, India
Najar, I., Department of Chemical Engineering, National Institute of Technology Srinagar, Srinagar, 190006, India
Srivastava, V.C., Department of Chemical Engineering, Indian Institute of Technology Roorkee, Roorkee, 247667, India
Pandey, A., Centre of Innovation and Translational Research, CSIR-Indian Institute of Toxicology Research, Lucknow, 226001, India, Centre for Energy and Environmental Sustainability, Lucknow, 226 029, India
Corresponding Author: Rasool, T.; Department of Chemical Engineering, India; email: tanveer@nitsri.ac.in
Appears in Collections:Journal Publications [CH]

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