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Title: Photocatalytical and Photochemical Generation of Imidoyl Radicals: Synthetic Applications
Authors: Sharma S.
Pandey A.P.
Sharma A.
Published in: Advanced Synthesis and Catalysis
Abstract: In the last few decades, the development in the field of radical chemistry has gained great attention. The majority of these radical strategies mainly depend on the in situ generation of reactive radical species by employing radical initiators such as oxidants and metal salts or methods such as photocatalysis and electrochemistry etc. This review covers the literature on the generation of imidoyl radicals using photoredox catalysis. In the majority of the reactions, the spontaneity of the underlying SET transitions is correlated by the compiled redox potential data of the reacting species for a better understanding of the readers. Besides, the applications of these reactive imidoyl radicals to access a variety of heterocycles such as benzothiazoles, indoles, quinoxalines, phenanthridines, isoquinolines, pyridines, and amides are also addressed.
Citation: Advanced Synthesis and Catalysis(2020), 362(23): 5196-5218
Issue Date: 2020
Publisher: Wiley-VCH Verlag
Keywords: Heterocycles
Radical reactions
Redox potential
SET transition
ISSN: 16154150
Author Scopus IDs: 57213924056
Author Affiliations: Sharma, S., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247667, India
Pandey, A.P., Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247667, India, Govt. PG College, Tikamgarh, Madhya Pradesh 47200
Funding Details: Council of Scientific and Industrial Research, India, CSIR: 02(0372)/19/EMRâ€II Ministry of Human Resource Development, MHRD.Financial support from CSIR (02(0372)/19/EMRâ€II), Govt. of India is gratefully acknowledged. SS and APP thanks MHRD for the Postâ€Doctoral Fellowship and Department of Higher Education Govt of Madhya Pradesh respectively.
Corresponding Author: Sharma, A.; Department of Chemistry, India; email:
Appears in Collections:Journal Publications [CY]

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