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Please use this identifier to cite or link to this item: http://repository.iitr.ac.in/handle/123456789/18105
Title: Energy storage performance of urea combustion derived nanocrystalline-Li2MnSiO4 as a novel electrode material for symmetric supercapacitor
Authors: Chaturvedi P.
Sil A.
Sharma Y.
Chitra R.Bhattacharya S.
Sahoo N.K.
Published in: Proceedings of AIP Conference
Abstract: A novel symmetric supercapacitor (SSC) consisting of urea combustion derived mesoporous Li2MnSiO4 (LMS) in aqueous electrolyte is investigated for the first time. The morphological and surface area analysis were conducted using FESEM and N2 adsorption/desorption measurements confirming the presence of mesopores with good surface area of nanocrystalline LMS. The electrochemical investigation of the SSC is examined using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) cycling, and the results are complimented with electrochemical impedance spectroscopy (EIS) in 2 M KOH aqueous solution. SSC exhibits the specific capacitance (Cs) of 40(±2) F g-1 at 3 mV s-1 and 42(±2) F g-1 at 0.1 A g-1 in voltage window ranging from -0.65 V to +0.65 V. GCD analysis illustrates good capacity retention and cyclability up to 1000 cycles. This improved performance of LMS in terms of rate capability, cyclability is mainly attributed to its unique morphology where high surface area and mesoporosity enables facile and smooth transportation of foreign electrolytic ions, and thereby increase the participation of active material in device. © 2016 Author(s).
Citation: Proceedings of AIP Conference, (2016)
URI: https://doi.org/10.1063/1.4947712
http://repository.iitr.ac.in/handle/123456789/18105
Issue Date: 2016
Publisher: American Institute of Physics Inc.
Keywords: Combustion
Electrochemical Impedance Spectroscopy
Li2MnSiO4
Mesoporous
Symmetric supercapacitor
ISBN: 9.78E+12
ISSN: 0094243X
Author Scopus IDs: 56556144400
7003754102
7103066055
Author Affiliations: Chaturvedi, P., Energy Storage Laboratory, Department of Applied Science and Engineering, IIT Roorkee, Saharanpur Campus, Saharanpur, 247001, India
Sil, A., Department of Metallurgical and Materials Engineering, IIT Roorkee, Roorkee, 247667, India, Center of Nanotechnology, IIT Roorkee, Roorkee, 247667, India
Sharma, Y., Energy Storage Laboratory, Department of Applied Science and Engineering, IIT Roorkee, Saharanpur Campus, Saharanpur, 247001, India, Center of Nanotechnology, IIT Roorkee, Roorkee, 247667, India
Corresponding Author: Sharma, Y.; Energy Storage Laboratory, Department of Applied Science and Engineering, IIT Roorkee, Saharanpur CampusIndia; email: yksptfpt@iitr.ac.in
Appears in Collections:Conference Publications [MT]

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